OSAKRYL. grades: OSA S20. Synthos Dwory 7 spółka z ograniczoną odpowiedzialnością spółka jawna - PDF

Page 1 z 7 Date of compilation (version no.): 2014/01/09 (2) Revision (revision no.): 2015/06/01 (1) Previous editions and revisions of this document have lost their validity SECTION 1. IDENTIFICATION

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Page 1 z 7 Date of compilation (version no.): 2014/01/09 (2) Revision (revision no.): 2015/06/01 (1) Previous editions and revisions of this document have lost their validity SECTION 1. IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY 1.1. Product identifier Osakryl OSA S Relevant identified uses of the mixture and uses advised against Identified uses Production of coatings Uses of coatings by industrial and professional users. Uses advised against None Details of the supplier of the safety data sheet ul. Chemików Oświęcim Poland Tel Fax Emergency telephone number (the number is available 24/7) SECTION 2. HAZARDS IDENTIFICATION 2.1. Classification of the mixture Classification in accordance with Regulation (EC) No 1272/2008 Eye Irrit. 2 H319 Causes serious eye irritation 2.2. Label elements Hazard pictogram: GHS07: exclamation mark Signal word: Warning Hazard statements: H319: Causes serious eye irritation. Precautionary statements: P264: Wash water thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention Other hazards The product contains no substances that meet the criteria for PBT or vpvb in accordance with Annex XIII. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substance Not applicable Page 2 z Mixtures This product is a mixture. Information on components in accordance with requirements of Annex II to REACH Regulation Alcohols, C10-16, ethoxylated, sulfates, sodium salts (Nr CAS: , Nr WE: , Index No.: N/A, REACH Registration No.: -, concentration: 1%, classification in accordance with Regulation 1272/2008: Eye Dam. 1, H318; Skin Irrit. 2, H315) SECTION 4. FIRST AID MEASURES 4.1. Description of first aid measures Inhalation In normal conditions of use and storage the product creates no danger via inhalation exposure. In case person exposed to product feels unwell it should be removed from the place of exposure to fresh air. Provide calm. In case symptoms persist consult a physician Skin contact Remove all contaminated clothing and shoes. Wash contaminated skin with plenty of water and soap. Consult a physician in case of skin irritation Eye contact Thoroughly rinse eyes with plenty of water for at least 15 minutes while lifting the eyelids. Check for and remove (if any and if possible) contact lenses (unless they adhered to eyes). Consult a physician in case an irritation has developed Ingestion/swallow Consult a physician 4.2. Most important symptoms and effects, both acute and delayed Upon direct contact with the product susceptible persons may suffer from skin/eye irritations Indication of any immediate medical attention and special treatment needed None. SECTION 5. FIRE FIGHTING MEASURES The product is a non-combustible material. SECTION 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Avoid contact with the product. Follow advice and instructions of emergency responders For emergency responders Avoid contact with the product. Wear work clothing and personal protective equipment Environmental precautions Cover drains, grates and manholes in order to prevent the product from entering the sewage or effluent systems Methods and material for containment and cleaning up Methods and material for containment If possible attempt to stop the leak and shut off the inflow. Embank the releasing liquid in case of large leaks Methods and material for cleaning up Small amounts of the product cover with sand or other absorbing material, collect to a labelled container and dispose of in accordance with regulations in force. Large amounts of released liquid pump over to a labelled container and use or dispose of in accordance with regulations in force Reference to other sections Page 3 z 7 SECTION 7. HANDLING AND STORAGE 7.1. Precautions for safe handling Observe basic regulations on occupational health, safety and hygiene as well as operating instructions at the workplace. Do not eat and drink when handling the product. Wear proper working clothing. If necessary, use personal protection equipment. Avoid direct contact with the product. Avoid contact with eyes. Ensure proper ventilation of the workplace Conditions for safe storage, including any incompatibilities Store in original tightly sealed containers at temperature 5 35 o C in well ventilated rooms outside this temperature range the dispersion may coagulate. For conditions to avoid and incompatible materials see Section 10 of this Specific end use(s) SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Occupational exposure limits None have been established DN(M)EL levels DN(M)EL levels workers DN(M)EL levels general population PNEC levels 8.2. Exposure controls Appropriate engineering controls Provide ventilation of the workplace Individual protection measures, such as personal protective equipment Eye/face protection If exposure of employees to sprayed or splashed particles of the product cannot be avoided use safety glasses or a face shield Skin protection Hand protection Not required. Other Wear work clothing and shoes Respiratory protection In case of insufficient ventilation wear mask with organic vapours filter Thermal hazards The product creates no thermal hazards Environmental exposure controls Avoid release to the environment. Do not discharge into drains. Emissions from vents and processing equipment have to be controlled in order to determine whether they are in compliance with in force regulations on environmental protection. Basing on results of such controls the need for implementation of relevant environmental risk management measures can be determined. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties a) Appearance liquid (water based dispersion) of white colour b) Odour characteristic Page 4 z 7 c) Odour threshold data not available d) ph 7,5 8,5 e) Melting point/freezing point data not available f) Initial boiling point and boiling range ca. 100 o C g) Flash point not applicable h) Evaporation rate not applicable i) Flammability (solid, gas) not applicable j) Upper/lower flammability or explosive limits not applicable k) Vapour pressure not applicable l) Vapour density not applicable m) Relative density ca. 1 g/cm 3 n) Solubility water-thinnable o) Partition coefficient: n-octanol/water not applicable p) Auto-ignition temperature not applicable q) Decomposition temperature data not available r) Viscosity(Brookfield) mpas s) Explosive properties not applicable t) Oxidising properties not applicable 9.2. Other information u) Heat of combustion not applicable v) Polymerization heat not applicable SECTION 10. STABILITY AND REACTIVITY Reactivity See Section 10.3 of this Chemical stability The product is stable under given herein conditions of use and storage. Use of stabilizers and/or antioxidants is not required Possibility of hazardous reactions None. Also see Section 10.5 of this Conditions to avoid At temperatures below 5 o C irreversible coagulation of the product occurs. At ca. 100 o C water contained in the product evaporates at noticeable rate Incompatible materials Avoid materials which exhibit hazardous reactions upon contact with water Hazardous decomposition products Thermal decomposition of contained in the product polymer starts at ca. 200 o C and is accompanied by formation and subsequent release of aromatic hydrocarbons. SECTION 11. TOXICOLOGICAL INFORMATION No data on toxicological properties of the product as such is available. Hazards which the product creates to the human health and life have been assessed in accordance with rules applicable for mixtures (see also Section 2 of this ) Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation The product complies with the classification criteria. The product can cause eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Page 5 z Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Information on likely routes of exposure Dermal, inhalation Symptoms related to the physical, chemical and toxicological characteristics The product can cause eye irritation Delayed and immediate effects as well as chronic effects from short and long-term exposure After direct contact with the eye, the product may cause an irritation. The reaction may develop several hours or several days after contact. SECTION 12. ECOLOGICAL INFORMATION No data on ecotoxicological properties of the product as such is available. Hazards which the product creates to the environment have been assessed in accordance with rules applicable for mixtures (see also Section 2 of this ) Toxicity The product is not classified as dangerous to the environment Persistence and degradability The main component of the product (polymer) does not undergo biodegradation, oxidation or hydrolysis at noticeable rate Bioaccumulative potential Based on chemical structure it is expected that the main component of the product (polymer) will not undergo bioaccumulation Mobility in soil Data not available Results of PBT and vpvb assessment The product contains no substances which have been identified as PBT/vPvB Other adverse effects SECTION 13. DISPOSAL CONSIDERATIONS Waste treatment methods Primary, product wastes should be recovered. Wastes, which could not be recovered should be biologically, chemically or physically transformed or stored on landfill. Landfilling should be performed only for those wastes, destruction of which is technically impossible or ecologically or economically unjustified. Recovery or destruction of product wastes has to be performed in accordance with regulations in force, in special assigned facility and/or equipment meeting the appropriate requirements. Waste code: the product itself: or Returnable packaging may be reused after decontamination. Disposable packaging has to be disposed of according to existing national, international and/or local disposal regulations. Example waste code: used containers, rigorously scraped out and containing dried residues of the supplied product: plastic packaging metal packaging. Page 6 z 7 Rigorously scraped out means removing the maximum amount of product from the container by physical or mechanical means (draining or scraping) to leave a residue or contamination that cannot be removed by such means. These codes have been assigned based on the actual composition of the product both as supplied and as dried residues. If mixed with other wastes, the waste codes quoted may not be applicable. SECTION 14. TRANSPORT INFORMATION Transport and packaging of the product are not subject to regulations on transport of hazardous goods (ADR, RID, IATA DGR, IMDG). Transport the product using covered means of transport UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the mixture REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (including any amendments/adaptations to technical progress). REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (including any amendments/adaptations to technical progress). DIRECTIVE 2008/98/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 19 November 2008 on waste and repealing certain Directives (including any amendments/adaptations to technical progress). Water hazard class: WGK Chemical safety assessment The supplier has not carried out chemical safety assessment for the mixture. In accordance with provisions of REACH regulation carrying out of chemical safety assessment for this product is not required. SECTION 16. OTHER INFORMATION Revised sections 2, List of relevant R phrases, hazard statements, safety phrases and/or precautionary statements given under Sections 2 to 15 and (if applicable) full text of any statements which are not written out in full under the aforementioned Sections H318 Causes serious eye damage H315 Causes skin irritation DN(M)EL Derived No (Minimal) Effect Levels PNEC Predicted No Effect Concentration Page 7 z 7 LD50 LC50 EL50 vpvb PBT Dose at which observed the death of 50% of the test animals The concentration at which observed the death of 50% of the test animals Level that causes adverse effects in 50% of the exposed population Very persistent and very bioaccumulative (substance) Persistent, bioaccumulative and toxic (substance) This document is of an informative character. The information given herein is based on the present state of our knowledge and experience. It makes neither product properties nor qualitative parameters guarantee and cannot be used as a basis of any claims. The information provided is not applicable for any mixtures of the product with any other materials. The product has to be transported, stored and used in accordance with regulations in force, good occupational hygiene practice and recommendations given its.
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